Why SYM 200? If you are starting in Germany, you have access to any number of cheap reliable used bikes for the same price. Something like a Honda that has parts support anywhere in the world.
You could go from Greece to Berlin entirely within Schengen (ferry from Piraeus to Bari and up Italy). Any third-party insurance you buy in Greece will already come with a Green Card that will be valid in most of the Balkans (except Kosovo I think?).
Entirely feasible and I'm sure you will have lots of fun until you hit Germany and have to avoid the autobahns.
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