Hey. These are common questions on Middle East visa applications. Don't stress about them.
For Destination, just put the capital city. For "Exact Address," just pick a hotel that looks good to you in the guidebook... if you have a guidebook. That's it.
You don't have to actually go to the hotel on your application if you don't want. It doesn't really matter because, wherever you check in, the hotel takes all your information and reports you to the authorities anyway. They will always know where you are, unless you stay with someone in their home... then they lose you and get a little nervous.
Have fun in Syria. It's a cool country and it's an interesting time to be there. (I'll be there in about a month.) Tensions might be a little high. Stay safe.
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