All I know is the stretch from Ghanzi up north to Bagani, Popa Falls in the Caprivi region. This is mostly sealed road. Just the short piece fom the BOT border to Popa Falls is dirt road (2006). In Ghanzi I turned westwards to NAM. Fuel is available in Maun and Bagani.
The eastern road from Katima Mulilo - Ngoma Gate - Kasane - Francistown is sealed as well. Fuel is available in every bigger settlement. Between Ngoma Gate & Kasane the road leads through the Chobe NP. You might come across wildlife, even elephants. There was lots of e-dung on the road ;-) So, don't travel by night...
Good luck!
Hans
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