My girlfreind did the same as yours.
No experince and we rode out of the centre of Mexico City, 12 months later we are back in Australia after travelling up to Canada and across Japan and Russia.
Only a couple of prangs and she is itching for more, I need a rest.
It will be stressful watching her negotiate traffic. Try and keep your cool, and keep an eye on her late in the day. As fatigue sets in the riding deteriates super fast and they start to hit every pot hole around and beet themselves up fast. Stop when you have to. Some days you wont get far, others you will cover great distances. Dont rush her and dont loose it with her. Defend her at all times in traffic if you can, not always possible.
And have a ball. Get the best travel Insurance you can.
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