Cape Town embassy is your best bet I reckon, they seemed to be very straightforward and helpful there.
We did our visa there, but had a letter of invitation faxed from Luanda (from a friend who was working there at the time, and a word of warning: fax was VERY hard to find in Luanda - in the end I think he got it faxed through some famous luxury hotel's staff help). It was positive and got it within 5 days if I remember. That's a proper 30-day visa to look around of this little explored and little known country of Angola.
If this fails then opt for that 5 day transit visa which should be easier.
Good luck,
Margus
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