I think most of Ukraine is pretty boring. While it's not boring enough to avoid if you have to pass through it, I'm not sure if I would go out of my way either, with a couple of exceptions, like the Crimea, which is a long way from where you'll be. I've also heard that the area around the Hungarian (?) border is nice, I think around Chernigov (?), but have never been myself.
While Ukraine's border is not particularly challenging, it will involve a couple of hours in each direction, and I am not sure it is worth it, would probably rather be relaxing in southern Poland or wherever.
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