Transnistria could cause some problem only if you are moving from Ukraine to Romania trough Moldavia. In such case, since Moldavia doesn’t recognize Transnistria you will have to explain to Moldavian Border police how did you get enter into Moldavia without having in your passport a Moldavian entry stamp (the one provided by Transnistria “authorities” is not valid, since is not an official Moldavian entry stamp).
On the contrary, moving from Romania, to Moldavia then Transnistria and finally Ukraine is not a big deal.
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